21 research outputs found

    CHLOROBENZENE AS A DIFFERENTIATING SOLVENT FOR THE OSCILLOMETRIC TITRATION OF WEAK ORGANIC BASES

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    Carrier Frequency Offset Estimation Algorithm in the Presence of I/Q Imbalance in OFDM Systems

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    In this paper, we analyzed the feasibility of using a virtual carrier based carrier frequency offset estimation algorithm in the presence of I/Q imbalance in OFDM systems. Based on the analysis of the signal model with both receiver CFO and I/Q imbalance impairment we conclude that it is feasible to extending the virtual carrier based CFO estimation algorithm to the I/Q imbalance scenario. The CFO estimation performance is evaluated through computer simulation. Impact of parameters on the estimation performance is investigated and it is consistent with our analysis. After CFO correction, a blind based I/Q imbalance estimation and compensation algorithm is applied. The final detection performance demonstrates that the virtual carrier based CFO estimation performance is good enough for subsequent I/Q imbalance estimation and compensation

    A convenient preparative method for the glucosides of fatty alcohols and sterols

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    132-13

    Mortality and pulmonary complications in patients undergoing surgery with perioperative SARS-CoV-2 infection: an international cohort study

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    Background: The impact of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) on postoperative recovery needs to be understood to inform clinical decision making during and after the COVID-19 pandemic. This study reports 30-day mortality and pulmonary complication rates in patients with perioperative SARS-CoV-2 infection. Methods: This international, multicentre, cohort study at 235 hospitals in 24 countries included all patients undergoing surgery who had SARS-CoV-2 infection confirmed within 7 days before or 30 days after surgery. The primary outcome measure was 30-day postoperative mortality and was assessed in all enrolled patients. The main secondary outcome measure was pulmonary complications, defined as pneumonia, acute respiratory distress syndrome, or unexpected postoperative ventilation. Findings: This analysis includes 1128 patients who had surgery between Jan 1 and March 31, 2020, of whom 835 (74·0%) had emergency surgery and 280 (24·8%) had elective surgery. SARS-CoV-2 infection was confirmed preoperatively in 294 (26·1%) patients. 30-day mortality was 23·8% (268 of 1128). Pulmonary complications occurred in 577 (51·2%) of 1128 patients; 30-day mortality in these patients was 38·0% (219 of 577), accounting for 81·7% (219 of 268) of all deaths. In adjusted analyses, 30-day mortality was associated with male sex (odds ratio 1·75 [95% CI 1·28–2·40], p\textless0·0001), age 70 years or older versus younger than 70 years (2·30 [1·65–3·22], p\textless0·0001), American Society of Anesthesiologists grades 3–5 versus grades 1–2 (2·35 [1·57–3·53], p\textless0·0001), malignant versus benign or obstetric diagnosis (1·55 [1·01–2·39], p=0·046), emergency versus elective surgery (1·67 [1·06–2·63], p=0·026), and major versus minor surgery (1·52 [1·01–2·31], p=0·047). Interpretation: Postoperative pulmonary complications occur in half of patients with perioperative SARS-CoV-2 infection and are associated with high mortality. Thresholds for surgery during the COVID-19 pandemic should be higher than during normal practice, particularly in men aged 70 years and older. Consideration should be given for postponing non-urgent procedures and promoting non-operative treatment to delay or avoid the need for surgery. Funding: National Institute for Health Research (NIHR), Association of Coloproctology of Great Britain and Ireland, Bowel and Cancer Research, Bowel Disease Research Foundation, Association of Upper Gastrointestinal Surgeons, British Association of Surgical Oncology, British Gynaecological Cancer Society, European Society of Coloproctology, NIHR Academy, Sarcoma UK, Vascular Society for Great Britain and Ireland, and Yorkshire Cancer Research

    Aroma Chemicals by Direct Hydration/Etherification of Olefins: An Industrial Approach

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    692-693α-Terpineol and dimethyl phenyl carbinol are prepared in excellent yields (85 per cent) by contacting an azeotropic mixture of the corresponding olefins, limonene or α-pinene and α-methylstyrene, with a strong cation exchange resin (H+ form). The corresponding methyl and ethyl ethers are prepared likewise by replacing water in the reaction mixture with methanol and ethanol respectively. While the methyl ethers are obtained in 75-80 per cent yield, the ethyl ethers are accompanied by the corresponding alcohols in equal proportion, in overall yield of 60-75 per cent
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